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244112 Sigma-Aldrich

Titanium(IV) butoxide

reagent grade, 97%

Synonym: Orthotitanic acid tetrabutylester, TNBT, TYZOR® TBT organic titanate, Tetrabutyl orthotitanate, Tetrabutyl titanate

  • CAS Number 5593-70-4

  • Linear Formula Ti(OCH2CH2CH2CH3)4

  • Molecular Weight 340.32

  •  Beilstein/REAXYS Number 4148236

  •  EC Number 227-006-8

  •  MDL number MFCD00009433

  •  PubChem Substance ID 24854652

  •  NACRES NA.23

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Solution Deposition Precursors,
Quality Level   200
grade   reagent grade
assay   97%
form   liquid (or viscous liquid)
  liquid
refractive index   n20/D 1.491 (lit.)
bp   206 °C/10 mmHg (lit.)
density   1.00 g/mL at 20 °C (lit.)
SMILES string   CCCCO[Ti](OCCCC)(OCCCC)OCCCC
InChI   1S/4C4H9O.Ti/c4*1-2-3-4-5;/h4*2-4H2,1H3;/q4*-1;+4
InChI key   YHWCPXVTRSHPNY-UHFFFAOYSA-N

Description

Packaging

2 kg in glass bottle

5, 100, 500 g in glass bottle

Application

Used to prepare nanosized titania in the anatase form and ferroelectric Bi4Ti3O12 thin films. Used in the preparation of nanocrystalline TiO2 powders at room temperature.

Legal Information

TYZOR is a registered trademark of E. I. du Pont de Nemours and Company

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
RIDADR 
UN 1993C 3 / PGIII
WGK Germany 
WGK 1
RTECS 
XR1585000
Flash Point(F) 
107.6 °F - Pensky-Martens closed cup
Flash Point(C) 
42 °C - Pensky-Martens closed cup
Protocols & Articles

Articles

A Review of Mesoporous TiO2 Thin Films

Jinshu Wang*, Junshu Wu, Hongyi Li The Key Lab of Advanced Functional Materials, Ministry of Education China, School of Materials Science and Engineering, Beijing University of Technology, Beijing 10...
Keywords: Adsorption, Building blocks, Catalysis, Ceramics, Condensations, Cosmetics, Degradations, Diffraction, Eliminations, Evaporation, Materials Science, Oxidations, Polymerization reactions, Semiconductor, Separation, Sol-gel

Application Note: Preparation of Monodisperse Polymer Spheres

Monodisperse, surfactant-free polymer spheres for use as colloidal crystal templates can be easily obtained in reasonably large quantities. Typical synthesis methods for poly(methyl methacrylate) (PM...
Melissa A. Fierke
Material Matters 2008, 3.1, 13.
Keywords: Emulsion polymerization, Polymerization reactions, Precipitation, Sol-gel

Mesoporous Oxides and Their Applications to Hydrogen Storage

Solid-state hydrogen storage is attractive from a technological point of view, but has encountered tremendous challenges in terms of practical storage capacity and kinetics.1-3 Hydrogen sorption, whe...
Arlon J. Hunt1, Karl Gross2, Samuel S. Mao1
Material Matters Volume 4 Article 2
Keywords: Addition reactions, Adsorption, Applications, Catalysis, Chemical vapor deposition, Condensations, Deposition, Diffusion, Insecticides, Magnetic resonance spectroscopy, Material Matters, Methods, Microscopy, Nanomaterials, Photographs, Scanning electron microscopy, Size-exclusion chromatography, Sol-gel, Substitutions, Transmission electron microscopy

Mesoporous Titanium Dioxide Thin Films

Titanium dioxide (TiO2) is an important n-type semiconducting material that shows interesting characteristics such as photoswitchable surface wettability, high photocatalytic activity, bistable elect...
Jinshu Wang, Junshu Wu, Hongyi Li
Material Matters, Volume 7, Number 2, 2–6
Keywords: Adsorption, Building blocks, Catalysis, Ceramics, Condensations, Cosmetics, Degradations, Diffraction, Eliminations, Evaporation, Materials Science, Oxidations, Polymerization reactions, Semiconductor, Separation, Sol-gel

Surface-enhanced Solar Energy Conversion Systems Using Gold and Silver Nanoparticles

Sustainable, environment-friendly, and clean energy sources with sufficiently high production efficiency for practical application are highly desirable to meet the energy challenge of the 21st centur...
Shanlin Pan and Arunava Gupta
Material Matters, 2012 v7, n4
Keywords: Absorption, Catalysis, Chemical vapor deposition, Degradations, Deposition, Diffusion, Electronics, Organic electronics, Photovoltaics, Recombination, Renewable energy, Semiconductor, Separation, Solar cells

Thermoelectric Performance of Perovskite-type Oxide Materials - Material Matters, 2011, Volume 6, Number 4, 92–99

Lassi Karvonen, Petr Tomeš, Anke Weidenkaff* Laboratory for Solid State Chemistry and Catalysis Department of Mobility, Energy and Environment EMPA-Swiss Federal Laboratories for Materials Science an...
Lassi Karvonen, Petr Tomeš, Anke Weidenkaff
Material Matters, 2011, Volume 6, Number 4, 92–99
Keywords: Catalysis, Combustion, Degradations, Materials Science, Oxidations, Semiconductor, Substitutions

Thermoelectric Performance of Perovskite-type Oxide Materials - Materials Science

Lassi Karvonen, Petr Tomeš, Anke Weidenkaff* Laboratory for Solid State Chemistry and Catalysis Department of Mobility, Energy and Environment EMPA-Swiss Federal Laboratories for Materials Science an...
Keywords: Catalysis, Combustion, Degradations, Materials Science, Oxidations, Semiconductor, Substitutions

Peer-Reviewed Papers
15

References

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